Environmental and political concerns are generating a growing interest in alternative engine fuels such as biodiesel. Biodiesel is a renewable energy source produced from natural oils and fats, which can be used as a substitute for petroleum diesel without the need for diesel engine modification. In addition to being biodegradable and non-toxic, biodiesel is also essentially free of sulfur and aromatics, producing lower exhaust emissions than conventional gasoline whilst providing similar properties in terms of fuel efficiency.
The greatest drawback of using pure vegetable oils as fuels are their high viscosity, although this can be reduced by techniques such as dilution, micro-emulsification, pyrolysis or transesterification. Of these processes, the transesterification of vegetable oil triglycerides in supercritical methanol has been shown to be particularly promising, producing high yields of low-viscosity methyl esters without the need of a catalyst. Furthermore, these methyl esters have considerably lower flash points than those of pure vegetable oils.
Biodiesel: A Realistic Fuel Alternative for Diesel Engines describes the production and characterization of biodiesel, along with current experimental research work in the field. The book will be of great interest to advanced undergraduates, postgraduates and researchers in renewable energy, as well as to fuel engineers.
Table of Contents
1- Introduction
11 Introduction to Energy Sources12 Global Energy Sources and the Present Energy Situation13 Renewable Energy Sources131 Biomass Energy and Biomass Conversion Technologies132 Hydropower133 Geothermal Energy134 Wind Energy135 Solar Energy136 Biohydrogen137 Other Renewable Energy Sources
2- Biofuels21 Introduction to Biofuels22 Bioethanol23 Biomethanol24 Biohydrogen from Biomass by Steam Reforming241 Steamreforming Process242 Fuels from Biosyngas via FischerTropsch Synthesis25 Biodiesel26 Biooil27 Global Biofuel Scenarios3- Vegetable Oils and Animal Fats31 Use of Vegetable Oils and Animal Fats in Fuel Engines32 Vegetable Oil Resources321 Inedible Oil Resources33 Vegetable Oil Processing332 Vegetable Oil Refining34 The Use of Vegetable Oils as Diesel Fuel341 Physical and Chemical Properties of Vegetable Oils342 Direct Use of Vegetable Oils in Diesel Engines35 New Engine Fuels from Vegetable Oils352 Cracking of Vegetable Oils353 Pyrolysis Mechanisms of Vegetable Oils36 Gasolinerich Liquid from Sunflower Oil by Alumina Catalytic Pyrolysis37 Diesellike Fuel from Tallow Beef by Pyrolysis and Steam Reforming38 Converting Triglyceridederived Synthetic Gas to Fuels via FischerTropsch Synthesis39 Triglyceride Analyses310 Triglyceride Economy4- Biodiesel41 Introduction to Biodiesel Concept 42 History43 Definitions44 Biodiesel as an Alternative to Diesel Engine Fuel45 Sources of Biodiesel
5- Biodiesel from Triglycerides via Transesterification51 Biodiesel from Triglycerides via Transesterification
511 Catalytic Transesterification Methods512 Supercritical Alcohol Transesterification513 Biocatalytic Transesterification Methods514 Recovery of Glycerine516 Esterification of Fatty Acids with Diazomethane518 Enzymecatalyzed Processes6- Fuel Properties of Biodiesels61 Viscosity, Density, and Flash Point 62 Cetane Number Cloud Point and Pour Point63 Characteristics of Distillation Curves65 Water Content67 Advantages and Disadvantages of Biodiesels7- Current Technologies in Biodiesel Production71 Biodiesel Production Processes712 Biodiesel Production with Batch Processing713 Biodiesel Production with Continuous Process714 Biodiesel Production with Noncatalyzed Transesterification715 Basic Plant Equipment Used in Biodiesel Production8- Engine Performance Tests81 Engine Combustion Process and Combustionrelated Concepts82 Engine Performance Tests9- Global Renewable Energy and Biofuel Scenarios91 Global Renewable Energy Sources92 Renewable Energy Scenarios10- The Biodiesel Economy and Biodiesel Policy101 Introduction to the Biodiesel Economy102 Economic Benefits of Biodiesel103 Biodiesel Costs104 General Biodiesel Policy
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